Curt Wittig

Curt Wittig

Paul A. Miller Chair in Letters, Arts and Sciences and Professor of Chemistry and Biochemistry at University of Southern California

I was born and raised in rough parts of Chicago, brought misery into the lives of my teachers, and caused my parents to age at a quickened rate. Happenstance got me into the University of Illinois at Chicago with a 2.4 / 4 GPA. Things like that used to happen every so often back then. After nearly failing out, I caught fire, moved to Urbana-Champaign, receiving a BS and then the PhD in electrical engineering (EE) in 1970. Postdocs (EE at USC, Physical Chemistry at Cambridge (UK) and Berkeley) were followed by a faculty appointment in 1973 at USC in EE. These were wild times. It is amazing things worked out as well as they did. I reached the rank of Professor in EE, Physics, and Chemistry in 1979. With interest in EE fading, I transferred to the Chemistry and Physics Departments in 1981, settling eventually in Chemistry. My research was and continues to be in Chemical Physics.

Notes Project

I have worked for over a decade on a set of notes that can prove use­ful in a range of ped­a­go­gi­cal environments: class­room, seminars, tutorials, studying, etc. They are organized into five reason­ably stand-alone Parts: I. Poly­atomic Molecules; II. Complexity in Poly­atomic Mole­cules; III. Miscellanea; IV. Phonons, Plas­mons, Pol­aritons, and More; V. Intro­duc­tion to Clas­si­cal and Quantum Relativity.

Each Part con­sists of pdf files for each chapter. The chapters are rea­son­ably self-contained and broken down into sections and subsections.

Part III, Miscellanea contains individual writeups that have proven useful: a course on gra­phene, lec­tures on cyclotron reso­nance, tutorials on vibronic interac­tions in pyr­azine, a foray into quantum op­tics, etc. and topics that arise fre­quently such as Fermi’s Golden Rule and the Kramers-Kronig rela­tions. Part III has just begun. I expect it to grow at a good pace during the first year and continue though at a reduced pace thereafter.

Part I - Polyatomic Molecules

I.1 Born-Oppenheimer Approximation and Nonadiabatic Coupling(87 pages)

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I.2 Intersections (63 pages)

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I.3 Conical Intersection (30 pages)

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I.4 Landau-Zener Model (28 pages)

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I.5 Geometric Phase (112 pages)

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I.6 Electrodynamics Miscellanea (66 pages)

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II.1 Couplings Among Bound States (55 pages)

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II.2 Effective Hamiltonians (70 pages)

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II.3 Resonances in One Dimension (91 pages)

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II.4 Unimolecular Reactions (91 pages)

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II.5 Couplings Between Discrete Sates and Continua (77 pages)

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  • Kramers-Kronig Relation
  • Fermi’s Golden Rule
  • Classical and Mathematical Origins of Quantum
  • Classical Oscillators
  • Graphene, Cyclotron Resonance
  • Vibronic Interactions
  • Quantum Optics
  • etc.

Part IV-A: Phonons, Plasmons, Polaritons, and More

IV-A.1. Particle-on-a Ring (25 pages)

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IV-A.2. Transfer Matrices (20 pages)

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IV-A.3. Hückel Model (24 pages)

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IV-A.4. Infinite One-Dimensional Lattice (73 pages)

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IV-A.5. Simple Molecular Orbital View (7 pages)

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Part IV.B: Phonons, Plasmons, Polaritons & More

IV.B.1 Lattice Vibrations in One Dimension (54 pages)

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IV.B.2. Heat Capacity and Thermal Conductivity (38 pages)

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IV.B.3. Insulators, Metals, and Semiconductors (45 pages)

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IV.B.4. Plasmas in Metals and Semiconductors (62 pages)

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IV.B.5. Nanoscale Plasmas (25 pages)

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IV.B.6. Phonon Polariton (28 pages)

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IV.B.7. Plasmon Polariton (24 pages)

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IV.B.8. Continuous Fields, Time Dependence, Infinite 3D (18 pages)

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IV.B.9. Extension to Covariant Field Theory (11 pages)

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IV.B Appendices (40 pages)

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V.1. Classical Special Relativity of Material Objects (116 pages)

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V.2. Electrodynamics (70 pages)

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V.3. Aharonov-Bohm Effect and Geometric Phase (58 pages)

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V.4. Introduction to Relativistic Quantum Mechanics (84 pages)

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Appendices (84 pages)

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